Physics applied to electrochemistry: Tunneling reactions
نویسندگان
چکیده
In this work, we explore how electrochemical tunneling reactions can be understood within the single-particle picture. That is, formal approach in which band diagrams are typically utilized to understand electronic processes solid-state materials and devices. This perspective is based upon Gerischer–Hopfield description of electron transfer at solid–liquid interfaces. Both single multiple discussed, as related voltammetric concepts trends. The impact nuclear quantization on also addressed, well its compact representation two probe phenomena low temperatures (often referred Franck–Condon blockade). manner, a linking presented.
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ژورنال
عنوان ژورنال: Journal of Applied Physics
سال: 2021
ISSN: ['1089-7550', '0021-8979', '1520-8850']
DOI: https://doi.org/10.1063/5.0039263